Expectation value: <math> \left \langle \hat A \right \rangle \equiv \left \langle \Psi \mid \hat A \mid \Psi \right \rangle </math> Probability that system is between <math>\overline{q} </math> and <math> \overline{q} + d \overline{q}</math> is <math>\Psi^*(\overline{q}, t) \Psi (\overline q, t) d \overline q</math> Scalar product (0 if orthogonal): <math> \left \langle \Psi (x) \mid \phi (x) \right \rangle \equiv \int_{}^{} \Psi (x)^* \phi (x)\, dx </math> Momentum: <math> \hat P = \frac{\hbar}{i} \vec \nabla </math> Position: <math> \hat R = \hat r </math> Energy: <math> \hat H (\hat x, \hat p)=i\hbar\frac{\partial }{ \partial t} =\frac{\hat P ^2}{2m}+V(\hat x) = \frac{\hat P ^2}{2m}=\frac {-\hbar^2}{2m} \frac{ \partial^2 }{ \partial x^2} +V(\hat x) </math> <math> \frac{\hat P ^2}{2m}=\frac {-\hbar^2}{2m} \frac{ \partial^2 }{ \partial x^2} </math> Time-dependent Schr��dinger's equation: <math>\hat H \Psi = i \hbar \frac{\partial \Psi}{\partial t} </math> General soluion to Schr��dinger's equation: <math> \Psi(x,t)= \sum_{E} c_E u_E (x) \mathrm{e}^{-\mathrm{i} Et/ \hbar} </math> where <math> c_E </math> are the eigenfunctions of the Hamiltonian that has eigenvalues of E Fermi function: <math>f(\epsilon)=\frac{1}{e^{\frac{\epsilon_c - \mu}{k_B T}}+1}</math> Density of states: <math>g(\epsilon)</math> <math>f(E) = \frac{1}{1 + e^{\frac{E-E_F}{kT}}}</math> <math>[\hat H, \hat P] = 0</math> momentum is s constant of motion Spherical harmonics: <math>u(\vec r) = \phi (r) \Psi (\phi, \theta)</math> |